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Radiocarbon (¹⁴C) is a critical tool for understanding the global carbon cycle. During the Anthropocene, two new processes influenced¹⁴C in atmospheric, land and ocean carbon reservoirs. First,¹⁴C-free carbon derived from fossil fuel burning has diluted¹⁴C, at rates that have accelerated with time. Second, ‘bomb’¹⁴C produced by atmospheric nuclear weapon tests in the mid-twentieth century provided a global isotope tracer that is used to constrain rates of air–sea gas exchange, carbon turnover, large-scale atmospheric and ocean transport, and other key C cycle processes. As we write, the¹⁴C/¹²C ratio of atmospheric CO₂is dropping below pre-industrial levels, and the rate of decline in the future will depend on global fossil fuel use and net exchange of bomb¹⁴C between the atmosphere, ocean and land. This milestone coincides with a rapid increase in¹⁴C measurement capacity worldwide. Leveraging future¹⁴C measurements to understand processes and test models requires coordinated international effort—a ‘decade of radiocarbon’ with multiple goals: (i) filling observational gaps using archives, (ii) building and sustaining observation networks to increase measurement density across carbon reservoirs, (iii) developing databases, synthesis and modelling tools and (iv) establishing metrics for identifying and verifying changes in carbon sources and sinks. This article is part of the Theo Murphy meeting issue 'Radiocarbon in the Anthropocene'. 

ABSTRACT Radiocarbon observations (Δ 14 C) in dissolved inorganic carbon (DIC) of seawater provide useful information about ocean carbon cycling and ocean circulation. To deliver high-quality observations, the Laboratory of Ion Beam Physics (LIP) at ETH-Zurich developed a new simplified method allowing the rapid analysis of radiocarbon in DIC of small seawater samples, which is continually assessed by following internal quality controls. However, a comparison with externally produced 14 C measurements to better establish an equivalency between methods was still missing. Here, we make the first intercomparison with the National Ocean Sciences Accelerator Mass Spectrometry (NOSAMS) facility based on 14 duplicate seawater samples collected in 2020. We also compare with prior deep-water observations from the 1970s to 1990s. The results show a very good agreement in both comparisons. The mean Δ 14 C of 12 duplicate samples measured by LIP and NOSAMS were statistically identical within one sigma uncertainty while two other duplicate samples agreed within two sigma. Based on this small number of duplicate samples, LIP values appear to be slightly lower than the NOSAMS values, but more measurements will be needed for confirmation. We also comment on storage and preservation techniques used in this study, including the freezing of samples collected in foil bags. 

The past century has been a time of unparalleled changes in global climate and global biogeochemistry. At the forefront of the study of these changes are regular time-series observations at remote stations of atmospheric CO 2 , isotopes of CO 2 , and related species, such as O 2 and carbonyl sulfide (COS). These records now span many decades and contain a wide spectrum of signals, from seasonal cycles to long-term trends. These signals are variously related to carbon sources and sinks, rates of photosynthesis and respiration of both land and oceanic ecosystems, and rates of air-sea exchange, providing unique insights into natural biogeochemical cycles and their ongoing changes. This review provides a broad overview of these records, focusing on what they have taught us about large-scale global biogeochemical change.